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For your objective, spill-resistant and ding resistant, you're dealing with two parameters that could be combined. As noted in Bill Horvath's answer, the weight will be a factor. Cardboard for concrete forms is pretty durable and somewhat moisture resistant "out of the box", and could take mild abuse without modification. Virtually any paint will ...

I'm not 100% sure what you mean by a "cat wheel", but if you're talking about a wheel in which your cats will run (like those put in hamster cages), one thing I'd try is lining it with sisal twine run back and forth in rows around the inside of the tube and glued down to the surface using wood glue like Elmer's or Gorilla Glue. That's how my (...